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Mosaic multistate scenario versus one-state description of supercooled liquids

Academic Article
Publication Date:
2007
abstract:
According to the mosaic scenario, relaxation in supercooled liquids is ruled by two competing mechanisms: surface tension, opposing the creation of local excitations, and entropy, providing the drive to the configurational rearrangement of a given region. We test this scenario through numerical simulations well below the Mode Coupling temperature. For an equilibrated configuration, we freeze all the particles outside a sphere and study the thermodynamics of this sphere. The frozen environment acts as a pinning field. Measuring the overlap between the unpinned and pinned equilibrium configurations of the sphere, we can see whether it has switched to a different state. We do not find any clear evidence of the mosaic scenario. Rather, our results seem compatible with the existence of a single (liquid) state. However, we find evidence of a growing static correlation length, apparently unrelated to the mosaic one.
Iris type:
01.01 Articolo in rivista
Keywords:
GLASS-FORMING LIQUIDS; LENGTH SCALE; TRANSITION; HETEROGENEITY; DYNAMICS
List of contributors:
Verrocchio, Paolo; Cavagna, Andrea
Authors of the University:
CAVAGNA ANDREA
Handle:
https://iris.cnr.it/handle/20.500.14243/167492
Published in:
PHYSICAL REVIEW LETTERS (PRINT)
Journal
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URL

http://prl.aps.org/abstract/PRL/v98/i18/e187801
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