Conjugate addition-elimination reactions as a novel synthetic route to dialkylated alpha,beta-unsaturated diesters
Academic Article
Publication Date:
1996
abstract:
The paper describes a novel synthetic route for mono- and dialkylation of dimethyl 2-phenylseleno fumarate 1. The conjugate additions to 1 proceed regio- and stereoselectively. The subsequent oxidative eliminations of phenylseleno group provide a convenient procedure for the synthesis of the title compounds.
Iris type:
01.01 Articolo in rivista
Keywords:
dimethyl 2-phenylseleno fumarate; organolithiums; Michael addition; dimethyl 2; 3-diakyl fumarate
List of contributors:
D'Onofrio, Franco
Published in: