Resonant two-photon ionization of van der Waals adducts of 4-fluorostyrene with monomethylamine and monoethylamine: Intracluster chemical reactions

Resonance-enhanced two-photon ionization of van der Waals complexes of 4-fluorostyrene clustered with some amines has been studied. The intracluster ionic chemistry leading to dissociative charge transfer and substitution reactions is discussed on the basis of experiments and structure calculations.