Effect of Asymmetric Mode on CO2 State-to-State Vibrational-Chemical Kinetics

Coupled state-to-state vibrational-chemical kinetics, gas dynamics, and heat transfer in the five-component mixture of dissociated CO2 are studied using the complete three-mode kinetic model and the reduced scheme involving mainly the vibrational states of the asymmetric mode. The emphasis is on the effect of asymmetric vibrations on the rate of dissociation, fluid dynamic variables, and heat flux. It is shown that intermode vibrational energy transitions between CO and CO2 asymmetric mode may considerably decrease the rate of dissociation; the presence of CO in the mixture quickly depletes high vibrational states and thus inhibits dissociation at low temperatures. The reduced model overpredicts populations of highly located states of the asymmetric mode, especially when intermode VV transitions are neglected; therefore, using the simplified model in flows with dominating dissociation may yield overestimated dissociation rate. In the hypersonic flow along the stagnation line, the influence of asymmetric vibrations on the fluid dynamics and heat transfer is weak; the main role belongs to chemical reactions and VT transitions in the bending mode. In this case, the computationally efficient simplified model can be used to predict macroscopic variables and heat flux without significant loss of accuracy.