A spectroscopic and structural characterization of the inclusion complexes of p-dimethylaminobenzonitrile with cyclodextrins
Academic Article
Publication Date:
2003
abstract:
The absorption and induced circular dichroism (icd) spectra of the alpha-CD:DMABN system in water solution at 20^ C evidenced the presence of 1:1 and 2:1 complexes. The beta-CD:DMABN system was found to be characterized by 1:1 and 2:2 associates. The association constants and the absolute absorption and icd spectra of each species was determined by dynamic Monte Carlo (DMC) calculations including solvation effects and induced circular dichroism calculations.
Iris type:
01.01 Articolo in rivista
Keywords:
TICT; p-dimethylaminobenzonitrile; circular dichroism; cyclodextrins
List of contributors:
Bortolus, Pietro; Monti, Sandra; Marconi, Giancarlo; Manoli, Francesco
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