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Dynamical ionization of the 4He trimer: A time-dependent modeling of its fragmentation

Academic Article
Publication Date:
2003
abstract:
He-4 trimer 3D-photoionization has been studied using a new quantum time-dependent model based on a wavelet expansion of the time-dependent vibrational self-consistent-field equations. Dissociation probabilities and final vibrational populations of the fragment molecules, together with time-snapshots of the angular distributions during fragmentation, are analyzed. Special emphasis is given to the internal vibrational rearrangements occurring during the fragmentation process following the photoionization event. Our calculations found (He-2(+))* to be preferentially formed in one of its vibrationally excited states and also that the amount of (He-3(+))* surviving the fragmentation, is mostly left in vibrationally excited states involving its ionic part.
Iris type:
01.01 Articolo in rivista
List of contributors:
Gianturco, Francesco; Satta, Mauro
Authors of the University:
SATTA MAURO
Handle:
https://iris.cnr.it/handle/20.500.14243/31733
Published in:
THE JOURNAL OF CHEMICAL PHYSICS
Journal
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URL

http://jcp.aip.org/resource/1/jcpsa6/v118/i6/p2606_s1
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