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Dynamical heterogeneities in irreversible gels: analogy with spin glasses

Academic Article
Publication Date:
2009
abstract:
We describe the sol-gel transition by introducing an order parameter, defined as the average of local variables, and its fluctuations. It can be shown that these quantities are related to percolation quantities, but in principle they can be measured without resorting to connectivity properties. In this framework it appears that the dynamical transition associated with gelation is a real thermodynamic transition, as happens in spin glasses. The strong analogies between the sol-gel transition and the spin glass transition are also discussed.
Iris type:
01.01 Articolo in rivista
Keywords:
MOLECULAR-DYNAMICS SIMULATIONS; ATTRACTION; POLYMERS
List of contributors:
DE CANDIA, Antonio; Coniglio, Antonio; Fierro, Annalisa
Authors of the University:
FIERRO ANNALISA
Handle:
https://iris.cnr.it/handle/20.500.14243/3178
Published in:
JOURNAL OF PHYSICS. CONDENSED MATTER (PRINT)
Journal
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URL

http://iopscience.iop.org/0953-8984/21/50/504110/
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