Publication Date:
2002
abstract:
The solvation of some neutral and charged organic molecules (phenol,
nitroanilines, tetraalkylammonium) in binary solvent mixtures has been
investigated by means of intermolecular 1H-NOESY NMR spectroscopy. The
solvation shell of the solute is, in most cases, selectively enriched in
one of the cosolvents (preferential solvation). The origin of preferential
solvation is discussed in terms of solute-solvent interactions and
microheterogeneity in the solvent mixture.
Iris type:
01.01 Articolo in rivista
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