Applications of N-phosphinoyloxaziridines in the conversion of alkenes to epoxides and esters to ?a-hydroxyesters

Academic Article
Publication Date:
2003
abstract:
N-Phosphinoyloxaziridines possessing an activating 3-CF3 substituent oxidise alkenes to epoxides at 35-45°C. Esters can be oxidised to á-hydroxyesters via their lithium enolates by various 3-subsituted N-phosphinoyloxaziridines. Stereoselectivity is observed in both these oxidations.
Iris type:
01.01 Articolo in rivista
Keywords:
Alkenes; reactions; Epoxides; N-Phosphinoyloxaziridines
List of contributors:
Authors of the University:
Handle:
https://iris.cnr.it/handle/20.500.14243/29726
Published in:
SYNLETT
Journal