Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [³-SiW10O36]8 : A Totally Inorganic Oxygen-Evolving Catalyst
Articolo
Data di Pubblicazione:
2008
Abstract:
Solid state and solution evidence confirms the embedding of an adamantane like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h(-1).
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
SUBSTITUTED POLYOXOMETALATE; WATER OXIDATION; photosynthesis; RUTHENIUM(IV)
Elenco autori:
Bonchio, Marcella
Link alla scheda completa:
Pubblicato in: