Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [³-SiW10O36]8 : A Totally Inorganic Oxygen-Evolving Catalyst
Academic Article
Publication Date:
2008
abstract:
Solid state and solution evidence confirms the embedding of an adamantane like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h(-1).
Iris type:
01.01 Articolo in rivista
Keywords:
SUBSTITUTED POLYOXOMETALATE; WATER OXIDATION; photosynthesis; RUTHENIUM(IV)
List of contributors:
Bonchio, Marcella
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