Iridium-catalyzed N-alkylation of diamines with glycerol

Academic Article

Publication Date:

2014

abstract:

N-alkylation of 1,2-diaminocyclohexanes with glycerol in water, catalyzed by [Cp*IrCl2 ]2 , gives a mixture of 2-methyldecahydroquinoxaline and 2-(1-hydroxyethyl)-3a,4,5,6,7,7a-hexahydro-1H-benzimidazoles.

Iris type:

01.01 Articolo in rivista

Keywords:

Glycerol valorization; Iridium catalyst; Hydrogen transfer reaction (HTR); Hydrogen borrowing; Amine alkylation with glycerol

List of contributors:

Crotti, Corrado

Handle:

https://iris.cnr.it/handle/20.500.14243/263673

Published in:

JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL

Journal