Membrane reactor for water gas shift reaction

In this experimental study the water gas shift (WGS) reaction is considered as a particular application of a catalytic membrane reactor (CMR). Experiments on the WGS reaction were carried out using a composite palladium membrane obtained by coating an ultrathin double-layer palladium film on the inner surface of the support of a commercial tubular ceramic membrane by a so-called co-condensation technique. The best operating conditions were determined at various H20/C0 molar ratios, temperature, Plumen, gas feed flow, and with and without nitrogen sweep gas. For a non-porous stainless steel tube and for the commercial ceramic membrane having the same geometrical dimensions, the conversion results are always lower than the equilibrium value. For the composite palladium membrane, the conversion also depends on the flow of the sweep gas utilized. For example, using a nitrogen sweep gas flow of 28.2 cm3/min, the maximum conversion value reaches 99.89%. The study of the effect of temperature on conversion of carbon monoxide in the WGS reaction shows that at higher reaction temperature, the thermodynamic equilibrium conversion of CO decreases. In contrast for the CMR considered in this work, there is a maximum conversion value around 600 K. This value is a compromise between the kinetic rate of the reaction (which increases with increasing temperature) and thermodynamic considerations for the WGS reaction. The effect of the time factor (W/F) on conversion of CO, with and without sweep gas at three different temperatures (595, 615 and 633 K) shows that at greater W/F there are correspondingly higher values of the CO conversion for each temperature considered. For each temperature there is a slight effect of the sweep gas, and this is higher at 595 K. The good performance of the composite ceramic-palladium membrane is confirmed by a comparison with experimental results recently presented in the literature for the same reaction. Reaction tests have been carried out for a feed mixture also. In this case, however, the resulting values are always below the equilibrium ones.