Reaction of platinum acetate with phosphines and molecular structure of trans-[Pt(OAc)2(PPh3)2]
Academic Article
Publication Date:
2003
abstract:
An improved synthesis of platinum acetate is reported in detail. This tetrameric complex reacts with PPh3 or Pn-Bu3 at room temperature to give the thermodynamically unstable bis-substituted trans-[Pt(OAc)2L2] complexes, which are not easily accessible via other routes. The structure of the new compound trans-[Pt(OAc)2(PPh3)2] has been determined by X-ray analysis.
Iris type:
01.01 Articolo in rivista
Keywords:
Platinum acetate; Platinum(II) complexes; Phosphino complexes; Acetato complexes; trans Complexes
List of contributors:
Benetollo, Franco; Venzo, Alfonso
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