Data di Pubblicazione:
2012
Abstract:
We address the in-plane pressure-dependent electrodynamics of graphite through synchrotron-based infrared
spectroscopy and ab initio density functional theory calculations. The Drude term remarkably increases upon
pressure application, as a consequence of an enhancement of both electron and hole charge densities. This is due
to the growth of the band dispersion along the kz direction between the K and H points of the Brillouin zone.
On the other hand, the mid-infrared optical conductivity between 800 and 5000 cm-1 is almost flat, and very
weakly pressure dependent, at least up to 7 GPa. This demonstrates a surprising robustness of the graphene-like
universal quantum conductance of graphite, even when the interlayer distance is significantly reduced.
spectroscopy and ab initio density functional theory calculations. The Drude term remarkably increases upon
pressure application, as a consequence of an enhancement of both electron and hole charge densities. This is due
to the growth of the band dispersion along the kz direction between the K and H points of the Brillouin zone.
On the other hand, the mid-infrared optical conductivity between 800 and 5000 cm-1 is almost flat, and very
weakly pressure dependent, at least up to 7 GPa. This demonstrates a surprising robustness of the graphene-like
universal quantum conductance of graphite, even when the interlayer distance is significantly reduced.
Tipologia CRIS:
01.01 Articolo in rivista
Keywords:
grafene; DFT; ottica
Elenco autori:
Lupi, Stefano; Bernardini, Fabio; Massidda, Sandro; Postorino, Paolo
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