Publication Date:
2004
abstract:
A product study of the reaction of benzyldimethylamine (1) with thermally and photochemically generated 1O2 in MeCN was carried out.
Benzaldehyde and N-benzyl-N-methylformamide are the reaction products, oxygenation representing ca. 9% of the overall quenching of 1O2 by
1. The temperature effect and the intermolecular and intramolecular kinetic deuterium isotope effects were also determined. It is suggested
that the products derive from an intracomplex hydrogen atom transfer in a reversibly formed charge-transfer complex.
Benzaldehyde and N-benzyl-N-methylformamide are the reaction products, oxygenation representing ca. 9% of the overall quenching of 1O2 by
1. The temperature effect and the intermolecular and intramolecular kinetic deuterium isotope effects were also determined. It is suggested
that the products derive from an intracomplex hydrogen atom transfer in a reversibly formed charge-transfer complex.
Iris type:
01.01 Articolo in rivista
Keywords:
Benzyldimethylamine; Oxygen
List of contributors:
Lapi, Andrea; Baciocchi, Enrico
Published in: