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TRIGONAL CONFIGURATION OF DISULFONYL CARBANIONS

Academic Article
Publication Date:
1986
abstract:
One-bond C-H coupling constants of the anionic carbon of anions derived from disulphones (1)-(3) provide unequivocal evidence for the trigonal hybridization of the charged carbon, previously assigned as tetrahedral; it is shown that the 1,3-dithiolane 1,1,3,3-tetraoxide undergoes ring opening upon treatment with strong bases.
Iris type:
01.01 Articolo in rivista
List of contributors:
Ferraccioli, Raffaella
Authors of the University:
FERRACCIOLI RAFFAELLA
Handle:
https://iris.cnr.it/handle/20.500.14243/174528
Published in:
JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS
Journal
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