Publication Date:
2007
abstract:
Based on computer simulations of the primitive model of electrolytes, we show that the effective interaction between low-charge colloids in solvents of low or moderate dielectric constant depends crucially on the salt concentration. While in the absence of salt the interaction is repulsive in agreement with Derjaguin-Landau-Verwey-Overbeek theory, depletion of salt Bjerrum pairs around the colloids leads to an attraction between like-charge colloids even at small salt concentrations. Copyright (C) EPLA, 2007.
Iris type:
01.01 Articolo in rivista
Keywords:
IONIC FLUIDS; ATTRACTION; MODEL; DEPLETION
List of contributors:
Tartaglia, Piero; Sciortino, Francesco; Zaccarelli, Emanuela
Published in: