Enhanced durability of a cost-effective perovskite-carbon catalyst for the oxygen evolution and reduction reactions in alkaline environment

The design of a bifunctional air electrode able to carry out both the oxygen reduction and
evolution reactions in an alkaline environment is essential for the progress of newgeneration
energy conversion and storage devices. Alkaline systems allow the use of
non-noble metals, which favors a considerable reduction of the system cost. In this
work, a cost-effective perovskite, La0.6Sr0.4Fe0.8Co0.2O3, has been investigated as bifunctional
catalyst in a 6 M KOH alkaline solution. The perovskite was mixed with an
experimental carbon black, characterized by a graphitic structure and a specific surface
area of 220 m2 g1. The perovskite-carbon composite was compared to a Pd/C catalyst
(employing the same carbon black as support). Generally, bifunctional catalysts are
subjected to high electrochemical potentials, particularly during the oxygen evolution. In
order to assess the stability of the bifunctional catalyst, several accelerated degradation
tests were performed. Results proved that the perovskite-carbon composite showed good
performance for both reactions, in particular for the oxygen evolution. Furthermore, it
also presented enhanced stability vs. Pd/C when subjected to degradation tests, maintaining
a constant potential over time, even working at high current densities (80 and
125 mA cm2). This material is envisaged as a very promising bifunctional catalyst, in
particular in terms of durability.