Thermal behavior and morphological and rheological properties of polypropylene and novel elastomeric ethylene copolymer blends

The thermal behavior including melting and crystallization behavior,
morphological and rheological properties of the blends based on an
isotactic polypropylene and a novel maleated elastomeric ethylene
copolymer are investigated in this work. Addition of elastomer to PP
is found not to change the PP crystalline structure significantly when
cooled quickly from the melt. On recrystallization at a lower cooling rate, the elastomer promotes the formation of ƒÒƒ{pseudohexagonal ƒnPP in
PP-rich blends. In elastomer-rich compositions, heterogeneous nucleation is hindered and homogeneous nucleation takes place. These phenomena are
revealed by morphology observation that with the increasing of the
elastomer content, the system undergoes PP continuous, dual-phase continuity and PP dispersed morphologies. The blends viscosity at low
shear rate range increases continuously with increasing elastomer
content and shows positive deviations from the additivity rule. In the terminal zone, the dynamic storage modulus of the blends shows positive
deviation from the simple mixing rule and the maximum deviation lies in the composition range of dual-phase continuity which could be caused
by a large increase in the interfacial tension. The Cox-Merz rule does not hold for the blends because of the two phase heterogeneous structure
and its variation in steady and oscillatory shear flow.