Mono- and bi-functional heterogeneous catalytic transformations of terpenes and terpenoids

Selective reactions of terpenes, catalyzed by different heterogeneous systems, are reported. -pinene and limonene epoxides can
be effectively isomerized to carbonyl compounds (selectivity >70%) over silica aluminas that appear to be good alternatives to
homogeneous ZnBr2. The different reactivity of geometric isomers can be used to separate them. Unsaturated ketones can be
converted through a two-step one-pot reaction in cyclic or bicyclic ethers through a bifunctional process involving a hydrogenation
and an acid-catalyzed step. However, the choice of the solvent allows to inhibit the acidic sites, thus obtaining a selective
hydrogenation reaction. On the other hand, the acidic reaction alone can be useful for alcohol epimerization and epimer separation.
Grafting of Ti in a siliceous matrix gives rise to a material with both redox and acidic properties. Solids obtained in this way are
active and selective in the epoxidation of terpenic alcohols but can also promote bifunctional reactions.